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新書推薦： 《 债务机器：美国的银行政策与个人陷阱 》 售價：NT$ 359.0 《 朝鲜半岛古代史研究 》 售價：NT$ 826.0 《 钱穆：国史新论 》 售價：NT$ 354.0 《 洪武元年：大明开国的罪与罚 》 售價：NT$ 302.0 《 大学问·从东方到中亚——19世纪的英俄“冷战”（1821—1907） 》 售價：NT$ 411.0 《 元宴 》 售價：NT$ 978.0 《 米兰讲稿（翁贝托·埃科作品系列） 》 售價：NT$ 1030.0 《 无线重构世界：射频技术的过去、现在与未来 》 售價：NT$ 562.0

編輯推薦： 1.内容全面，符合我国当前发展重点，内容涉及资源高效清洁转化及多级循环利用集成技术和绿色过程工程研究成果的回顾、总结与展望。 2.参考性强，本书对于工业绿色清洁发展相关从业人员具有重要的指导意义，对学科发展也大有裨益。 3.作者张懿院士是我国清洁生产研究领域主要开拓者之一，本书收录了作者及其团队在绿色过程工程与清洁生产技术方面成果，共计130余篇代表性学术论文。 內容簡介： 本书选登了中国科学院过程工程研究所张懿院士的130余篇学术论文，内容分为总论、亚熔盐绿色化工冶金平台技术、重化工业环境污染治理技术与工程、热点与前沿领域四大主题。本书还附有张懿院士的照片资料、学术成长经历及学术成就、承担的主要科研项目、主要获得奖励和社会兼职等内容，展示了张懿院士科学研究、学术交流及培育人才的经历与成就。 本书充分反映了张懿院士在绿色过程工程方面做出的学术贡献，可供从事绿色化工的科研人员、技术人员参考，也可供高等学校化学工程与工艺、环境科学与工程及相关专业师生参阅。 本书选登了中国科学院过程工程研究所张懿院士的130余篇学术论文，内容分为总论、亚熔盐绿色化工冶金平台技术、重化工业环境污染治理技术与工程、热点与前沿领域四大主题。本书还附有张懿院士的照片资料、学术成长经历及学术成就、承担的主要科研项目、主要获得奖励和社会兼职等内容，展示了张懿院士科学研究、学术交流及培育人才的经历与成就。 本书充分反映了张懿院士在绿色过程工程方面做出的学术贡献，可供从事绿色化工的科研人员、技术人员参考，也可供高等学校化学工程与工艺、环境科学与工程及相关专业师生参阅。 關於作者： 张懿，中国科学院过程工程研究所院士，研究员，是我国清洁生产研究领域主要开拓者之一。八十年代开创了资源材料化学化工与环境工程交叉综合研究的过程污染控制新方向，建立了系列新技术和优 秀示范工程，在海内外产生重要影响。九十年代开拓了清洁工艺-绿色化学化工过程研究新方向，主持我国首 个清洁生产工艺国家项目，在资源高效清洁转化-多级循环利用集成技术和绿色过程工程领域取得了重要原创性成果和产业化应用突破。在国内外首次提出的亚熔盐高效清洁反应分离新系统和新过程，已拓展为处理多种矿物资源的普适性新理论和共性技术。运用化学工程的原理及方法强化传统环境工程技术，也取得系统性理论和工程应用成果。对资源环境过程工程交叉学科建设和我国传统产业的绿色化升级和循环经济模式建设做出了开创性贡献。研究成果获得国 家技术发明二等奖2项、三等奖1项，国 家科技进步二等奖、三等奖各1项，省部级科技奖7项，发表论文300多篇（SCI收录200余篇），专著合著13部。获国 家授权发明专利50余项，培养博、硕士研究生70余名。 目錄： 第1章总论 绿色过程工程 张懿2 SUB-MOLTEN SALT ENVIRONMENTALLY BENIGN TECHNOLOGY Yi ZHANG, Zuo-Hu LI, Hong-Bin XU, Shi-Li ZHENG, Tao QI, Hui-Quan LI8 绿色化学与铬盐工业的新一代产业革命 张懿，李佐虎，王志宽，陈家镛18 新一代资源回收循环集成技术与生态化产业体系 张懿，陈家镛，刘会洲26 清洁生产与循环经济 张懿30 原子经济性 张懿36 绿色制造技术发展趋势 张懿，徐滨士，段广洪43 第2章亚熔盐绿色化工冶金平台技术 2.1亚熔盐绿色过程基础49 Comparison of the Oxygen Reduction Reaction between NaOH and KOH Solutions on a Pt Electrode： The Electrolyte-Dependent Effect Wei Jin,Hao Du, Shili Zheng,Hongbin Xu, and Yi Zhang49 The influence of KOH concentration, oxygen partial pressure and temperature on the oxygen reduction reaction at Pt electrodes Wen-Yi Yan, Shi-Li Zheng, Wei Jin, Zhong Peng, Shao-Na Wang, Hao Du, Yi Zhang63 Structure and Diffusivity of Oxygen in Concentrated Alkali-Metal Hydroxide Solutions： A Molecular Dynamics Simulation Study L Ye-Qing,ZHENG Shi-Li,WANG Shao-Na,DU Hao， ZHANG Yi81 Indirect Electrochemical CrⅢ Oxidation in KOH Solutions at an Au Electrode： The Role of Oxygen Reduction Reaction Wei Jin, Michael S. Moats, Shili Zheng,Hao Du,Yi Zhang, and Jan D. Miller97 Improved electrochemical CrⅥ detoxification by integrating the direct and indirect pathways Wei Jin, Hao Du, Kai Yan, Shili Zheng, Yi Zhang109 Electrochemical CrⅢ Oxidation and Mobilization by In Situ Generated Reactive Oxygen Species in Alkaline Solution Yudong Xue,Wei Jin, Hao Du, Shili Zheng,Zhi Sun, Wenyi Yan, and Yi Zhang117 Vibrational spectra and molecular dynamics of hydrogen peroxide molecules at quartzwater interfaces Ye-qing Lv, Shi-li Zheng, Shao-na Wang, Wen-yi Yan, Yi Zhang, Hao Du130 Effect of microbubble diameter, alkaline concentration and temperature on reactive oxygen species concentration Xiaobin Yu, Zhonghang Wang,Yeqing Lv, Shaona Wang,Shili Zheng, Hao Du， and Yi Zhang148 Electrochemical detoxification and recovery of spent SCR catalyst by insitu generated reactive oxygen species in alkaline media Yudong Xue, Yang Zhang, Ying Zhang, Shili Zheng, Yi Zhang, Wei Jin162 Electrochemical enhanced oxidative decomposition of chromite ore in highly concentrated KOH solution Zhonghang Wang, Hao Du, Shaona Wang, Shili Zheng, Yi Zhang, Seyeon Hwang, Nam Soo Kim,Tae Eui Jeong180 Electrochemical decomposition of vanadium slag in concentrated NaOH solution Zhonghang Wang, Shili Zheng, Shaona Wang, Yaling Qin, Hao Du, Yi Zhang199 Phase Diagram for the System Na2O-Al2O3-H2O at High Alkali Concentration Yifei Zhang, Yinghui Li, and Yi Zhang211 Phase diagram for the Na2O-Al2O3-H2O system at 130℃ Shuhua Ma,Shili Zheng,Yifei Zhang，and Yi Zhang218 Solubility Data for the NaOH-NaNO3-Na3VO4-Na2CrO4-H2O System at 40 and 80 ℃ Shaona Wang, Ziwei Song, Yan Zhang, Hao Du, Shili Zheng,and Yi Zhang224 Phase Equilibria in the NaOH-Na2MoO4-Na2SO4-H2O System at 313.15 and 403.15 K Yan Liu, Yifei Zhang, Fangfang Chen, and Yi Zhang232 Isopiestic Study of the Na2CrO4-H2O System at 353.15K： Prediction of the Solubility of Na2CrO4 in Aqueous NaOH Solutions Wei Jin, Shili Zheng, Hao Du, Hongbin Xu, and Yi Zhang241 PotentialpH diagrams of Cr-H2O system at elevated temperatures YOU Hai-xia, XU Hong-bin, ZHANG Yi, ZHENG Shi-li, GAO Yi-ying250 Vapor Pressure Determination of the KOH K2CrO4 H2O System Shaona Wang,Shili Zheng,Hong-Bin Xu,and Yi Zhang259 Density and viscosity of aqueous solution of K2CrO4KOH mixed electrolytes GUO Ya-jie, XU Hong-bin, GUO Fen,ZHENG Shi-li, ZHANG Yi265 Solid-Liquid Equilibria of K2CO3 K2CrO4 H2O System Chunhua Du,Shili Zheng,Huiquan Li,and Yi Zhang272 Hydrodynamics of a Multi-Stage Internal Loop Airlift Reactor Shaoguo Li， Tao Qi， Yi Zhang， Changhou Liu278 Experimental investigation and CFD simulation of liquid-solid-solid dispersion in a stirred reactor Licheng Wang, Yifei Zhang, Xingang Li, Yi Zhang288 Na2O-CrO3-Al2O3-H2O四元水盐体系高碱区相图 邹兴，张懿312 Na2CrO4-NH42CrO4-H2O体系的相图 崔金兰，张懿，刘昌见317 Pitzer模型对Na ‖CrO2-4，HCO-3-H2O体系的溶解度计算与实验验证 刘昌见，张懿323 开发用于辅助流程模拟的物性数据库 王兵，赵岩，齐涛，张懿327 2.2铬盐清洁工艺与集成技术337 Green Manufacturing Process of Chromium Compounds Yi Zhang, Zuo-Hu Li, Tao Qi, Shi-Li Zheng, Hui-Quan Li, and Hong-Bin Xu337 Green chemistry of chromate cleaner production ZHANG Yi,LI Zuo-Hu，QI Tao,WANG Zhi-Kuan,ZHENG Shi-Li349 Green metallurgical processing of chromite S. Zheng, Y. Zhang, Z. Li, T. Qi, H. Li, H. Xu358 Oxidative leaching of a Vietnamese chromite ore in highly concentrated potassium hydroxide aqueous solution at 300℃ and atmospheric pressure H.-B. Xu, S.-L. Zheng, Y.Zhang, Z.-H. Li, Z.-K. Wang368 A New Method of Potassium Chromate Production from Chromite and KOH-KNO3-H2O Binary Submolten Salt System Zhi Sun, Yi Zhang, and Shi-Li Zheng,Yang Zhang384 Effect of mechanical activation on alkali leaching of chromite ore ZHANG Yang, ZHENG Shi-li, DU Hao, XU Hong-bin, ZHANG Yi404 Hydrogen Reduction： A Novel Method of Synthesizing Ultra-fine Chromic Oxide Powder BAI Yulan, XU Hongbin, ZHANG Yi411 An investigation on the kinetics of chromium dissolution from Philippine chromite ore at high oxygen pressure in KOH sub-molten salt solution Gang Chen, Jiajun Wang, Wang Xiaohui, Shi-Li Zheng, Hao Du, Yi Zhang417 铬铁矿液相氧化过程中材质腐蚀性能研究 郑诗礼，张懿435 铬酸钠氢还原反应动力学 尤海侠，徐红彬，张懿，李佐虎，郑诗礼，白玉兰441 低温氢还原活化烧结法制备氧化铬绿颜料 李平，徐红彬，张懿，李佐虎，郑诗礼448 铬盐清洁生产工艺中铝硅的脱除 王少娜，郑诗礼，张懿454 铬渣零排放绿色化工新过程 齐涛，张懿，郭跃华，李佐虎，王志宽463 2.3钒钛清洁工艺469 Decomposition of ilmenite by concentrated KOH solution under atmospheric pressure Yumin Liu, Tao Qi, Jinglong Chu, Qijie Tong, Yi Zhang469 A novel preparation of titanium dioxide from titanium slag Yongjie Zhang, Tao Qi, Yi Zhang477 Extraction behaviours of titanium and other impurities in the decomposition process of ilmenite by highly concentrated KOH solution Yu-min Liu, Hua L, Tao Qi, and Yi Zhang487 A novel method of leaching vanadium from extracted vanadium residue using sodium sub-molten salt medium Lanjie Li, Shili Zheng, Donghui Chen, Shaona Wang, Hao Du,Minglei Gao, and Yi Zhang496 A Novel Method to Extract Vanadium and Chromium from Vanadium Slag using Molten NaOH-NaNO3 Binary System Biao Liu,Hao Du, Shao-Na Wang, Yi Zhang, and Shi-Li Zheng,Lan-Jie Li Dong-Hui Chen506 Kinetics analysis of decomposition of vanadium slag by KOH sub-molten salt method Hui-bin LIU, Hao DU, Da-wei WANG, Shao-na WANG, Shi-li ZHENG, Yi ZHANG526 Intensified decomposition of vanadium slag via aeration in concentrated NaOH solution Longjie Liu, Zhonghang Wang, Hao Du, Shili Zheng, Ulla Lassi, Yi Zhang543 Crystallization and Separation of Potassium Vanadate in Highly Concentrated Potassium Hydroxide Solution Na Yang,Shili Zheng,Shaona Wang,Yaling Qin,Wanli Xie,Bingjing Zhou, and Yi Zhang558 The electrowinning of vanadium oxide from alkaline solution Biao Liu, Shili Zheng, Shaona Wang, Yi Zhang, Hao Du566 Cleaner production of vanadium oxides by cation-exchange membrane-assisted electrolysis of sodium vanadate solution Bo Pan, Wei Jin, Biao Liu, Shili Zheng, Shaona Wang, Hao Du, Yi Zhang579 Vanadium metabolism investigation using substance flow and scenario analysis Fangfang ZHANG, Huiquan LI, Bo CHEN, Xue GUAN, Yi ZHANG593 KOH亚熔盐法制备钛酸钾晶须和二氧化钛 仝启杰，齐涛，刘玉民，王丽娜，张懿609 活性炭强化氧化亚熔盐介质中钒渣分解机理 王少娜，王亚茹，杜浩，郑诗礼，张懿617 2.4氧化铝、钽铌清洁工艺及其他629 Spectra of sodium aluminate solutions MA Shu-hua, ZHENG Shi-li, XU Hong-bin,ZHANG Yi629 Preparation of sodium aluminate from the leach liquor of diasporic bauxite in concentrated NaOH solution Shaotao Cao, Yifei Zhang, Yi Zhang637 Nucleation and Morphology of Monosodium Aluminate Hydrate from Concentrated Sodium Aluminate Solutions Shaotao Cao, Yifei Zhang, and Yi Zhang650 Research on NaCaHSiO4 decomposition in sodium hydroxide solution Ran Zhang, Shuhua Ma, Quancheng Yang, Shili Zheng, Yi Zhang, Namsoo Kim, Sungik Hong661 Additives effects on crystallization and morphology in a novel caustic aluminate solution decomposition process Ying ZHANG, Shili ZHENG, Yifei ZHANG, Hongbin XU, Yi ZHANG679 Cleaner synthesis of mesoporous alumina from sodium aluminate solution Li Zhong, Yifei Zhang, and Yi Zhang686 Combined treatment of red mud and coal fly ash by a hydro-chemical process Chunli Liu, Shuhua Ma, Shili Zheng,Yang Luo, Jian Ding, Xiaohui Wang, Yi Zhang698 Study of extracting alumina from high-alumina PC fly ash bya hydro-chemical process Jian Ding, Shuhua Ma, Shili Zheng, Yi Zhang, Zongli Xie, Shirley Shen, Zhongkai Liu714 Leaching of a low-grade niobium-tantalum ore by highly concentrated caustic potash solution Hongming Zhou, Shili Zheng, Yi Zhang730 Kinetic Investigations on the Leaching of Niobium from a Low-Grade Niobium-Tantalum Ore by Concentrated KOH Solution ZHOU Hongming，ZHENG Shili, and ZHANG Yi739 Dissolution behaviors of Ta2O5, Nb2O5 and their mixture in KOH and H2O system WANG Xiao-hui, ZHENG Shi-li, XU Hong-bin, ZHANG Yi750 A novel method to prepare ultrafine potassium tantalate powders Xiaohui Wang, Shili Zheng, Yi Zhang760 Dehydration of tetrahydrate potassium pentaborate in fluidized bed Gang Yang, Zuohu Li, Yi Zhang765 Preparation and surface chemistry characteristics of pure and coated acicular -FeOOH particles Guo Yue-Hua, Zhang Yi773 铝酸钠溶液中过饱和氧化硅的稳定性 张亦飞，郑诗礼，张懿782 NaOH亚熔盐法处理拜尔法赤泥的铝硅行为 孙旺，郑诗礼，张亦飞，徐红彬，张懿787 一水硬铝石型铝土矿在KOH亚熔盐介质中的溶出行为 马青霞，张亦飞，曹绍涛，张懿794 高苛性化系数铝酸钠溶液深度脱硅 元炯亮，张懿804 甲醇溶析铝酸钠制备氢氧化铝 王雪，郑诗礼，张懿809 第3章重化工业环境污染治理技术与工程 3.1工业废水治理技术818 Recovery of heavy metals from electroplating sludge and stainless steel pickle waste liquid by ammonia leaching method Zhang Yi，Wang Zhi-kuan，Xu Xia，Chen Yong-qi，Qi Tao818 Electrochemical dechlorination of chloroacetic acidsCAAs using hemoglobin-loaded carbon nanotube electrode Yu-Ping Li, Hong-Bin Cao, Yi Zhang823 Electrochemical reduction of nitrobenzene at carbon nanotube electrode Yu-Ping Li, Hong-Bin Cao, Chen-Ming Liu, Yi Zhang831 A novel mechanism of bisphenol A removal during electro-enzymatic oxidative process： Chain reactions from self-polymerization to cross-coupling oxidation Haitao Li, He Zhao, Chenming Liu, Yuping Li,Hongbin Cao, Yi Zhang843 Novel technique for internal structure and elemental distribution analyses of granular sludge from reactors for wastewater treatment Xiaolei Cao，Hongbin Cao，Yuxing Sheng，Haixia You, Yi Zhang857 Optimal Design of Solvent Blend and Its Application in Coking Wastewater Treatment Process Mingsen Liao, Yuehong Zhao, Pengge Ning,Hongbin Cao,Hao Wen, and Yi Zhang864 Activated carbon-enhanced ozonation of oxalate attributed to HOoxidation in bulk solution and surface oxidation：Effects of the type and number of basic sites Linlin Xing, Yongbing Xie, Hongbin Cao, Daisuke Minakata, Yi Zhang, John C. Crittenden882 Desalination stability of capacitive deionization using ordered mesoporous carbon： Effect of oxygen-containing surface groups and pore properties Feng Duan, Xuan Du, Yuping Li, Hongbin Cao, Yi Zhang900 Activated carbon electrodes： Electrochemical oxidation coupled with desalination for wastewater treatment Feng Duan, Yuping Li, Hongbin Cao,Yi Wang, John C. Crittenden, Yi Zhang915 C3N4-MnCNT composite as a heterogeneous catalyst in the electro-peroxone process for promoting the reaction between O3 and H2O2 in acid solution Zhuang Guo, Linbi Zhou, Hongbin Cao，Yongbing Xie，Jiadong Xiao，Jin Yang, and Yi Zhang927 基于MINLP 模型的焦化废水蒸氨塔操作优化 廖明森，赵月红，宁朋歌，曹宏斌，温浩，张懿943 新型非均相电-Fenton 技术深度处理焦化废水 李海涛，李玉平，张安洋，曹宏斌，李鑫钢，张懿955 3.2工业固废资源化966 Preparation of high purity magnesium oxide and magnetic ferrite from chromium containing residue I. Mathematical model and experiments under atmospheric carbonate leaching Tao Qi，Yi Zhang，Yuehua Guo，Zuohu Li966 Preparation of high purity magnesium oxide and magnetic ferrite from chromium containing residue Ⅱ. Pressurized carbonate leaching and preparation of magnetic ferrite Yuehua Guo，Tao Qi，Yi Zhang，Zuohu Li，Jiashu Liu971 Preparation of monodispersed aragonite microspheres via a carbonation crystallization pathway Weijun Bao, Huiquan Li, and Yi Zhang976 Selective extraction and deep removal of tungsten from sodium molybdate solution by primary amine N1923 Pengge Ning, Hongbin Cao, Yi Zhang985 Separation of copper, ironⅢ, zinc and nickel from nitrate solution by solvent extraction using LK-C2 Xiaojuan Zhang, Xingang Li, Hongbin Cao, Yi Zhang999 Effects of various pretreatments on biological sulfate reduction with waste activated sludge as electron donor and waste activated sludge diminution under biosulfidogenic condition Yuxing Sheng, Hongbin Cao, Yuping Li, Yi Zhang1014 Experimental investigation of enhanced carbonation by solvent extraction for indirect CO2 mineral sequestration Weijun Bao, Huiquan Li, and Yi Zhang1028 A novel process for recycling and resynthesizing LiNi13Co13Mn13O2 from the cathode scraps intended for lithium-ion batteries Xihua Zhang, Yongbing Xie, Hongbin Cao，Faheem Nawaz, Yi Zhang1050 Selective extraction and deep separation of VⅤ and CrⅥ in the leaching solution of chromium-bearing vanadium slag with primary amine LK-N21 Pengge Ning, Xiao Lin, Hongbin Cao, Yi Zhang1068 The influence of impurities on Ga electrowinning：Vanadium and iron Ling Liu, Mingyong Wang, Zhi Wang, Yi Zhang1082 Insights into the extraction of various vanadium species by primary amine Jiawei Wen，Feng Liu, Hongbin Cao,Pengge Ning, Yi Zhang1094 Spent lead-acid battery recycling in China-A review and sustainable analyses on mass flow of lead Zhi Sun, Hongbin Cao, Xihua Zhang, Xiao Lin,Wenwen Zheng, Guoqing Cao, Yong Sun,Yi Zhang1105 Lithium Carbonate Recovery from Cathode Scrap of Spent Lithium-Ion Battery： A Closed-Loop Process Wenfang Gao, Xihua Zhang, Xiaohong Zheng,Xiao Lin,Hongbin Cao,Yi Zhang,Zhi Sun1125 Selective recovery of valuable metals from spent lithium-ion batteriesProcess development and kinetics evaluation Wenfang Gao, Jiali Song, Hongbin Cao,Xiao Lin, Xihua Zhang,Xiaohong Zheng, Yi Zhang, Zhi Sun1141 Evaluation on end-of-life LEDs by understanding the criticality and recyclability for metals recycling Sheng Fang, Wenyi Yan, Hongbin Cao,Qingbin Song, Yi Zhang, Zhi Sun1166 Selective recovery of lithium from spent lithium iron phosphate batteries： a sustainable process Yongxia Yang，Xiangqi Meng，Hongbin Cao，Xiao Lin，Chenming Liu，Yong Sun，Yi Zhang，Zhi Sun1188 A promising approach to recover a spent SCR catalyst： Deactivation by arsenic and alkaline metals and catalyst regeneration Meng Li, Biao Liu, Xinran Wang, Xiaobin Yu, Shili Zheng,Hao Du, David Dreisinger,Yi Zhang1210 第4章热点与前沿领域 4.1新型功能材料研发1226 The effect of electrolytic oxidation on the electrochemical properties of multi-walled carbon nanotubes Chen-Ming Liu,Hong-Bin Cao, Yu-Ping Li,Hong-Bin Xu,Yi Zhang1226 Reductive dehalogenation of haloacetic acids by hemoglobin-loaded carbon nanotube electrode Yu-Ping Li, Hong-Bin Cao, Yi Zhang1236 Promoting effect of nitration modification on activated carbon in the catalytic ozonation of oxalic acid Hongbin Cao, Linlin Xing, Guangguo Wu, Yongbing Xie,Shaoyuan Shi, Yi Zhang, Daisuke Minakata, John C. Crittenden1250 m-BiVO4 hollow spheres coated on carbon fiber with superior reusability as photocatalyst Toheed Ahmed,Hong-ling Zhang, Hong-bin Xu, Yi Zhang1266 The corrosion resistance of Ni anode and Ga electrowinning in alkaline sulfide solutions Ling Liu，Mingyong Wang，Zhi Wang，Yi Zhang1281 Amino-modification and successive electrochemical reduction of graphene oxide for highly sensitive electrochemical detection of trace Pb2 Mingjie Li, Zehui Li, Chenming Liu, Yu Chang,Jiawei Wen, He Zhao,Hongbin Cao, Yi Zhang, Dagang Liu1295 Amorphous-crystalline TiO2carbon nanofibers composite electrode by one-step electrospinning for symmetric supercapacitor Kexin Tang，Yuping Li, Hongbin Cao，Chunlei Su，Zisheng Zhang，Yi Zhang1309 Macropore-and Micropore-Dominated Carbon Derived from Polyvinyl alcohol and Polyvinylpyrrolidone for Supercapacitor and Capacitive Deionization Kexin Tang，Junjun Chang, Hongbin Cao，Chunlei Su，Yuping Li，Zisheng Zhang，and Yi Zhang1329 High-Rate and Long-Term Cycle Stability of Li-S Batteries Enabled by Li2STiO2-Impregnated Hollow Carbon Nanofiber Cathodes Xinran Wang，Xuanxuan Bi Shaona Wang，Yi Zhang,Hao Du，and Jun Lu1346 High-Rate Performance and Ultralong Cycle Life Enabled by Hybrid Organic-Inorganic Vanadyl Ethylene Glycolate for Lithium-Ion Batteries Xinran Wang，Xuanxuan Bi，Shili Zheng，Shaona Wang，Yi Zhang，Hao Du，and Jun Lu1361 Preparation of CrO2 nanoparticles via oxidation method Zhenzhao Pei，Hongbin Xu，Yi Zhang1377 Preparation of Cr2O3-based pigments with high NIR reflectance via thermal decomposition of CrOOH Shu-ting LIANG,Hong-ling ZHANG,Min-ting LUO,Hong-xia LIU,Yu-lan BAI,Hong-bin XU,Yi ZHANG1383 Synthesis,Characterization,and Boron Uptake of Organic-Inorganic Hybrid Mesoporous Materials Lina Wang,Tao Qi, and Yi Zhang1394 Influences of processing techniques of the H2O2-precipitated pseudoboehmite on the structural and textural properties of -Al2O3 Weiquan Cai,Huiquan Li,Yi Zhang1399 Properties of Water Blown Rigid Polyurethane Foams with Different Functionality LI Xiaobin,CAO Hongbin,ZHANG Yi1412 The vanadate adsorption on a mesoporous boehmite and its cleaner production application of chromate Ping Li,Sili Zheng,Penghui Qing,Yongan Chen,Lei Tian,Xiaodan Zheng,and Yi Zhang1421 Porous hexagonal boron nitride nanosheets with large adsorption capacity for Cu2synthesized through a two-step roasting process Jing Zhang,Hong-ling Zhang,Peng Zhou,Peng-hui Qing,Hong-bin Xu,Yi Zhang1436 碳酸盐热解法制备氧化镁晶须 王万平, 张懿1442 4.2绿色催化与循环经济1446 Preparation of monodispersed aragonite microspheres via a carbonation crystallization pathway Weijun Bao,Huiquan Li,and Yi Zhang1446 A non-phosgene route for synthesis of methylene diphenyl dicarbamate from methylene dianiline and methyl carbamate Yixia Pei,Huiquan Li,Haitao Liu,Yi Zhang 1455 Non-phosgene synthesis of isocyanates based on CO2： Synthesis of methyl N-phenyl carbamate through coupling route with lead compound catalysts Junjie Gao,Huiquan Li,Yi Zhang,Weiyang Fei1464 Variations of Structure and Active Species in Mesoporous Cr-MSU-x Catalyst during the Dehydrogenation of Ethane with CO2 L.-Ch.Liu,H.-Q. Li, and Y.Zhang1474 Oxidative Dehydrogenation of Ethane to Ethylene with CO2 over Fe-CrZrO2 Catalysts Shuang Deng,Songgeng Li,Huiquan Li,and Yi Zhang1485 Energy conservation and circular economy in Chinas process industries Huiquan Li,Weijun Bao,Caihong Xiu,Yi Zhang,Hongbin Xu 1496 Insights on the mechanism for synthesis of methylenedianiline from aniline and formaldehyde through HPLC-MS and isotope tracer studies Chen Ye Wang,Hui Quan Li,Li Guo Wang,Yan Cao,Hai Tao Liu,Yi Zhang 1513 钢铁生产流程污染贡献综合评价方法研究 修彩虹，李会泉，张懿1519 Bu2SnO催化反应耦合法清洁合成苯氨基甲酸甲酯 高俊杰，李会泉，张懿，费维扬1525 CrMSU-1催化剂中Cr含量对CO2氧化丙烷脱氢反应催化性能的影响 柳海涛，李会泉，杨玮娇，王兴瑞，张懿1535 循环型过程工业系统设计框架、策略与案例研究 李会泉，齐涛，郑诗礼，徐红彬，李佐虎，张懿1542 附录 张懿简历1547 学术成长经历及学术成就1548 主要获得的奖励及荣誉1551 主要社会兼职1552 主要论著列表1553 人才培养统计1554 硕士研究生1554 博士研究生1556 博士后1561 化学化工常见非法定计量单位和换算系数1562 內容試閱： 张懿院士八十岁华诞来临之际，我们作为张先生的学生和晚辈以十分崇敬的心情编纂了这本论文集精选。 中国工程院院士、环境与过程工程专家张懿是我国绿色过程工程的主要开拓者之一，在国际上首次从生产源头上彻底解决了铬盐行业重金属污染的难题,首次实现了铬渣的零排放和铬资源多组分深度利用的生态工业新模式，为我国国民经济的可持续发展做出了重要贡献。 1939年农历四月二十八日，张懿院士出生在黑龙江省牡丹江市。张懿从小学少先队大队长、初中的尖子生到1955年以优异成绩考取了东北最好的学校辽宁省实验中学高中。张懿院士在确定考大学也是国家需要后，选择了冶金物理化学专业，既有理科的攻坚，又能为东北冶金重工业服务。1958年报考东北工学院（现东北大学）冶金物化专业，以化学工程和物理化学为知识基础解决国民经济主体产业的发展问题。1963年张懿以东北工学院冶金物化全系总分第一名的成绩被学校分配到北京的中国科学院化工冶金研究所（现中国科学院过程工程研究所）陈家镛院士领导的湿法冶金研究室，从此她在中科院国家一流研究所的土壤上，在20世纪50年代回国的著名爱国科学家陈家镛（化学工程专家）、叶诸沛（化工冶金专家）、郭慕孙（化学工程专家）的指导下，在过程工程领域不断开拓创新，逐步建立了可解决我国资源环境瓶颈问题并引领未来发展的系列基础与应用研究的重要科技方向。 张懿院士在环境工程领域做出了开拓性贡献。20世纪80年代初，在工业污染治理社会需求急迫的背景下，张懿院士在国内率先将资源材料化学化工的最新成果和研究方法融合渗透到环境工程研究领域，开拓了资源材料化学化工与环境工程交叉综合研究的新方向，提出资源再生循环与无害化技术相结合的积极治理路线，主持完成了多项国家七五八五九五环保科技攻关及院部级重大项目，在重金属危险废弃物污染控制方向建立了多组分高效选择性提取、CrⅥ催化还原水解、萃取分离、铁氧体固定无害化、资源循环利用与酸碱废弃物协同治理等系列新技术和应用工程，建成国内外第一个多组分重金属污泥综合回收生产线。八五攻关主持完成的电镀污泥与铬渣资源化技术为我国重金属有害废弃物资源化提供了产业化集成技术。近年又完成了钒-铬废渣资源化、冶金行业氨氮废水处理、钢铁焦化行业焦化废水处理等环保难题的十多个产业化应用工程，具有化工过程强化环境治理的鲜明技术创新特色，较传统工艺大幅度提高了处理效率，高效回收资源，降低环境治理成本，获得了国家主管部门和企业的高度认可，为完成国家重点污染物减排指标做出了重要贡献。相关成果获国家奖5项，院部级奖7项，已发挥重大社会效益、环境效益和经济效益，促进了我国工业废弃物治理从消纳性处置提高到资源良性循环的新阶段。 随着时代发展和需求，20世纪90年代初，张懿院士准确把握了国内外资源环境领域技术发展趋势，在绿色过程工程领域做出了开拓性贡献。针对我国重化工业高速发展阶段的资源环境瓶颈问题，在中科院开拓了清洁生产工艺与技术研究新领域，率先由工业污染末端治理转向源头污染控制技术研究。张懿院士主持我国第一个清洁工艺国家攻关和863项目，从铬化工重污染行业切入，在国内外首次提出亚熔盐非常规介质低温高效清洁转化铬、铝、钒、钛、铌、钽、锆等多种两性金属矿产资源的原创性原子经济性反应新系统、新原理，建立了亚熔盐介质中活性氧组分对矿物矿相转化量化调控的理论和物理场协同强化技术，已在铬化工行业取得工业应用并成为国家认定的行业替代性清洁技术。该成果已于2005年获国家技术发明二等奖，为最终实现产业化应用，正在扩展为铝、钒、钛、钽、锆等两性金属亚熔盐清洁工艺的共性技术。该系列产业化集成技术可解决我国大宗特色难处理矿产资源综合利用和过程污染控制的资源-环境难题。 在清洁生产集成技术研究基础上，从企业和系统尺度，在国内最早从技术层面研究工业废弃物与过程物流质量交换集成网络构建的循环经济方法。所指导的河南义马市循环经济建设规划株洲清水塘循环经济工业园区规划为国家环境保护总局（现生态环境部）和国家发改委审批的国家级循环经济试点。作为国家循环经济规划和工业生态网络构建主要专家，多次主持与参加循环经济规划审定，为推动我国循环经济建设作出了重要奉献。 在绿色化学化工与环境化学基础研究方面，张懿院士发现并定义亚熔盐非常规介质，针对物质转化的化学活化，建立了亚熔盐非常规介质的全新化学、溶液模型与热力学计算方法，首次在分子水平解析亚熔盐介质中不同类型活性氧负离子原子（O2-、O-2、O2-2、HO-、O等）生成机理及赋存规律，形成亚熔盐非常规介质高效清洁新过程的系统理论和共性技术基础研究平台，对推动我国难处理资源高效清洁循环利用与材料研究奠定了重要理论基础。已获得国内外学术界与相关产业界的很高评价与认同，形成基础理论-应用技术-产业开发的良性科研模式。 张懿院士的研究团队获得2002年国家人事部、中国科学院授予的先进集体。张懿院士克己奉公，不拿现场补贴，还个人资助合作企业的困难职工，在合作单位树立了共产党员科学家的很高威信。她用自己的实践和人格魅力证实共产党人对科技事业的崇高追求，连续多年被评为中科院和中央国家机关优秀共产党员，2001年被评为中科院首届十大杰出妇女。 张懿院士敬业、团结、求实、创新，视名利淡如水，看事业重如山。数十载科研生涯，桃李满天下，春晖遍四方，一直默默为我国的资源环境科学事业忘我耕耘。在张懿院士80岁生日来临之际，编写组特整理了张懿发表的学术论著，精选编纂了这本《绿色过程工程与清洁生产技术》，记录了张懿院士所有的学术思想，在环境工程领域、绿色过程工程领域和工业生态网络构建工业循环经济建设方面的开拓性贡献，以及在绿色化学化工与环境化学基础研究方面的突出贡献。书中所收录的原论文、发表时间跨度较大，随时代发展，稿件中一些名词术语存在不同用法。为尊重历史原貌、保留原文风格，在文中不做统一、于书后附有非法定计量单位换算表，以供参考。 忆往昔，张懿院士对我们的谆谆教诲。岁月如梭，春秋轮回，衷心祝愿张懿院士：生命之树常绿，生命之水长流！ 本书编写组 2019年1月

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